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PV in the 1960s

Max Davis, December 18, 2009

For some quick entertainment, I thought I'd share a few scientific papers about PV from "back in the day".  From well before the 1977 founding of the Solar Energy Research Institute (now NREL), and back when oil was less than $20 a barrel (in 2009 dollars).

In 1963, the year the Beatles released their first album and Iron Man debuted as a comic book character, Joseph Loferski published "Recent Research on Photovoltaic Solar Energy Converters". This paper described silicon's lead as a material for high-efficiency (15% efficient, that is) solar cells, but mentioned some of the other materials under exploration, such as GaAs (13%), CdTe (6%), and CdS (6%). Note that the record 1-sun cell efficiencies of these materials are currently 25% (Si PERL cell, 1999), 26.1% (GaAs thin-film, from 2008 I believe), and 16.7% (CdTe, 2001).

In 1964, the year the Shinkansen high-speed rail system was inaugurated in Japan and Dr. Strangelove was released (and nominated for four Academy Awards), R. J. Tallent and E. J. Zapel published "Structrual and Electrical Performance of a Concentrating Solar Cell Panel". This paper described the design of a CPV module that used reflective aluminum to reach a 1.9x concentration ratio, as shown in the module and system test images below. I'm a fan of the Boeing Solar Research Laboratory bus.

Screenshot023

Screenshot021

And in 1965, the year of the civil rights march from Selma to Montgomery, DEC's unveiling of the PDP-8 microcomputer, and the first wide area network connection (between Massachusetts and California, the states that house the two GreenMountain Engineering offices), E. L. Ralph published "Use Of Concentrated Sunlight With Solar Cells For Terrestrial Applications", another early CPV paper describing a simple conical optic, the need for tracking, and an increase in efficiency with low concentration (via an increase in Voc), which must be balanced against losses due to series resistance and increased cell temperature.

Cheers and Happy Holidays!

This blog will likely go on hiatus until 2010, as we focus on wrapping up various end-of-year project work.

IV-Stat 3.1: Our free solar cell testing software

Nate Beckett, December 7, 2009

This summer GreenMountain quietly released a beta version of some solar cell characterization software we’ve been developing for the past few years.  Motivated by positive feedback and a recent update extending functionality to the newest Keithley Sourcemeter series, we’ve decided to leave beta.  So without further ado, I’m pleased to introduce IV-Stat 3.1. It’s free of charge: no fees, limited-time trials or ads.

IV-Stat_Main_Menu
The software allows measurement of solar device IV curves by interfacing with Keithley 24XX or 26XX(A) Series Sourcemeters. The program then performs a curve fit on the measured IV data to extract standard parameters (such as Isc, Voc, efficiency, Rse, Rsh, as well as more detailed parameters such as diode currents and ideality factors for various different one-diode or two-diode solar cell models).

Originally developed in 2006 for internal use, it has also been customized for our clients a number of times.  Currently there are versions being used in the R&D labs of a few well known solar companies and research labs.  The following is a testimonial by Keith Richtman of the Massachusetts Institute of Technology Laboratory for Photovoltaic Research:

“As a rapidly growing research lab, we needed software to support solar cell I-V testing without weeks of development time. GreenMountain engineers customized IV-Stat to provide exactly the features and flexibility we required and delivered quickly.”

GreenMountain’s core business is engineering design and consulting services, not selling software. Because of this, we’ve decided to give IVstat away for free (though as part of this, we can only offer minimal support). If it helps you, we hope you’ll keep us in mind as a team who can help you solve engineering problems and be successful as you scale up your technologies.

In IV-Stat we tried to include all of the functionally we felt the typical photovoltaic researcher would need:
  • Control of  the Keithley sweep settings
  • Control of  analysis variables
  • Raw data outputted in a spreadsheet-compatible format
  • Ability to save and load all of the test settings with configuration files
  • Simple tools for graphing the IV curves and saving images
  • The ability to use Pulse Mode (with 2430 or 26XXA Keithleys) for high current tests
If you need additional features or customization, this is something we can do for a one-time fee; feel free to give us a call, however I also wanted to point out one additional feature we’ve included: hooks.

IV-Stat includes two “hooks” which help users customize the software or integrate it with their own hardware. Twice during each sweep IV-Stat executes an external program (“hook”) and passes it the test data. A typical use of these hooks would be to trigger some external user program which could open and close the light source shutter, transfer the generated data to an SPC database (note that we’ve designed custom web-accessible manufacturing databases for a number of clients), measure a reference cell, or perform some other function.

One example of customization we’ve done in the past is integrating IV-Stat with a custom probe station we designed (see slick marketing picture below) and the client’s solar simulator and reference “champion” cell.  This probe station featured a custom thermal vacuum chuck, adjustable probe bars, and horizontal shuttle for easy access.  The result was a robust, semi-automated, research cell testing station.

IV-Stat_Probe_Frame

If you’re looking for more detailed technical information on IV-Stat, please review the product web page, the User Manual, or send me an email at iv_support@greenmountainengineering.com; I’ll be happy to answer any questions.

Cheers!

Grant Opportunities in Cleantech

Max Davis, November 30, 2009

There are a number of grant opportunities in the renewable energy sector. While we typically do not develop our own technologies and products (our core focus is engineering design services for clients in the cleantech sector), we do work on grants in partnership with other companies, typically as a subcontractor.

Often, a small company will have a technology or product idea they want to develop, and we can strengthen the application by providing our company resume (covering engineering in areas such as solar, wind, batteries, and biofuels) as a source of engineering experience, prototyping facilities, and a path to scale-up.

Here’s a list of the grant programs we keep an eye on (primarily focused on US grant opportunities)— we hope some of you find this useful!

International Grants:

Two grant agencies of interest are:

USTDA (US Trade and Development Agency): The USTDA’s mission is to promote economic growth in developing and middle income countries, while simultaneously helping American businesses export their products and services. It funds a number of projects in renewable energy. GreenMountain is the current recipient of a grant (as a subcontractor to Aviastructure) to design renewable energy systems for Colombia’s civil aviation. Our role involves technical site resource assessment (which has involved our engineers traveling to remote jungle sites all over Colombia) as well as system design and modeling for combinations of solar, wind, battery, and backup diesel systems using tools including HOMER.

World Bank: The World Bank organizes a number of grant and funding activities. The Lighting Africa project is an example of where GreenMountain took on the product engineering and design responsibilities as a subcontractor for a product sales partner. We were selected as one of the winners for our solar lighting design, though our partner decided not to further pursue the project for business reasons.

Note that members of the GreenMountain team also have significant international renewable energy experience through involvement in Engineers Without Borders (including former presidency of the San Francisco Professionals chapter), solar and water project development work in Tanzania and Haiti, founding members of the Appropriate Technology Design Team, and significant early design involvement in the Darfur Stoves project.

National Grants:

Grants.gov: The central resource for federal grants. It allows searches by keyword, agency, and so on. More specifically, the DOE: Energy Efficiency and Renewable Energy (EERE): is a central location for announcements of most DOE Funding Opportunities.

ARRA Funding by the DOE: Funding opportunities authorized through the Recovery Act.

DOE: Advanced Research Projects Agency Energy (ARPA E): Inspired by the Defense Advanced Research Projects Agency (DARPA), ARPA-E was created to support high risk, high reward energy research for climate change and energy security in areas that industry is not likely to undertake independently because of high technical or financial risk.

DOE Loan Guarantee Program: This program provides large-scale loan guarantees (up to hundreds of millions of dollars) for renewable energy generation and scale-up projects such as wind, solar, biomass, geothermal and hydropower. GreenMountain can contribute to a client’s Phase II engineering assessment requirements, per section C.9 of the Renewable Energy / Efficiency Solicitation.

DOE: Small Business Innovation Research (SBIR): Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) are U.S. Government programs in which federal agencies with large R&D budgets set aside a small fraction of their funding for competitions among small businesses only. Small businesses that win awards in these programs keep the rights to any technology developed and are encouraged to commercialize the technology. There are regular solicitations on a variety of topics.

DOE: Solar Energy Technologies Program: SETP funding opportunities encourage collaborative partnerships among industry, universities, national laboratories, federal, state, and local governments and non-government agencies and advocacy groups. You can also look at past winners of the SETP PV Pre-Incubator and of the SETP PV Supply chain and Cross-Cutting Program to get a feeling for what types of applications have been successful.

DOE: Biomass Program Solicitations: The Department of Energy is a major provider of funding for basic and applied research for converting biomass resources to biofuels. Many financial assistance opportunities are available for small to large scale research activities

DOE: Wind and Hydropower Technologies Program: The program sponsors research and development activities to enable greater use of two abundant domestic resources for electric power generation that will help stabilize energy costs, enhance energy security, and improve our environment.

DOE: Hydrogen, Fuel Cells, and Infrastructure Technologies: The mission of the DOE HFCIT Program is to research, develop, and validate hydrogen production, delivery, storage, and fuel cell technologies.

DOE: Vehicle Technologies Program: The DOE Office of Energy Efficiency and Renewable Energy (EERE) provides funding opportunities for advanced vehicle technology projects that are aimed at removing technical and cost barriers.

DOE Office of Science Financial Assistance Grant Program: Grant applications submitted to the Office of Science must fit within their list of program areas. You are encouraged to call the program area contact, to discuss your research project before you submit your application.

NSF: Energy for Sustainability: The Energy for Sustainability program supports fundamental research and education in energy production, conversion, and storage.Note that NSF does not normally support pilot plant efforts, the development of products for commercial marketing, or a variety of other areas. You can also view abstracts of recent awards.

NREL: Business Opportunity Solicitations: Opportunities to work with NREL.

ORNL: Opportunities: Opportunities to work with Oak Ridge National Lab. They jointly apply for a number of SBIR grants. They don't give out their own money, but put out requests for proposals to collaborate in specific areas.

Biomass Research & Development Initiative (BRDI): The Biomass Research and Development Initiative (BRDI) is the multi-agency effort to coordinate and accelerate all Federal bio-based products and bioenergy research and development.

DOE: Inventions and Innovation: This program appears to be inactive in the past few years.

Regional Grants:

This list is by no means comprehensive, but a few notable grant programs at the state level in California and Massachusetts are:

Energy Innovations Small Grant (EISG): This California Energy Commission program is designed to fill a fairly narrow research niche that focuses on early "proof of concept" research of new innovative energy ideas to determine if they are technologically and economically feasible. The subject area must target one a few specific areas listed on the web site, and grants are in the range of $50k-$100k.

PIER: California Energy Commission: The Energy Commission's Research Development and Demonstration (RD&D) Division supports public interest energy research, development, and demonstration. RD&D activities include providing contracts and grants for research and development of energy technologies and related scientific activities. See also: http://www.energy.ca.gov/contracts/renewables.html

Massachusetts Clean Energy Center (CEC): Prior to 2008, the Massachusetts Technology Collaborative (MTC) awarded grants in the renewable energy sector, but this responsibility has been transferred to the CEC. GreenMountain has worked for the MTC/CEC over the past three years, performing technical assessment and due diligence on relevant applications in a broad range of technology areas (solar, wind, algae oil and other biodiesel, Stirling engines, and so on).

Good luck!

Solar Scalability: Critical Metrics for Technology Assessment

Tyler Williams, November 23, 2009

Recently, in discussions of solar technology, I've been hearing more and more talk of scalability. Being a skeptical engineer, I chalked most of it up to marketing hype. It did get me thinking however, so recently I dug into it a bit to see if anything meaningful could be pulled out. My goal is not a policy plan or pitch for solar, but the following: 1) to see what metrics can be used in engineering design and technology development to quantify scalability, and 2) to imagine extremely large scale solar and see what innovations this might inspire.

Ambitious Goals

The first questions that frame a discussion of scalability are “how big?” and “how fast?” Every policy wonk seems to have a different version of what is best. Al Gore's goal is 100% carbon free electricity in 10 years. NREL’s Ken Zweibel and Cal Tech’s Nathan Lewis have both discussed various aspects of the “Terawatt Challenge” and have established a rough worldwide goal of 20 TW by 2050.

This isn’t a political blog, so I don’t want to argue about policy; this is a discussion of solar scalability. To bracket the problem, let’s say, in round numbers, that the target is to provide 1/3 of the current worldwide total energy consumption (electricity, transportation, and industrial/residential heat) using solar power by approximately 2025. As of 2008, the world was using energy at a rate of 15 TW with the U.S. accounting for about 22% of that (3.3 TW). To meet our goal, we need around 5 TW of total installed capacity by 2025. Of course, since solar only produces power during the day, it suffers from a pretty lousy capacity factor, so we’ll have to install 20-35 TW of peak capacity depending on location and module characteristics. To keep numbers round and to put a stake in the ground, I’m going to use a target of 25 TW, which is about 3500 times the current worldwide installed capacity.

Constraints on Ultimate Size?

Before addressing scaling rate concerns, what about ultimate size?  Solar energy has the largest fundamental resource base of all types of energy, at 120,000 TW total and 600 TW practically available.  In the following sections, we’ll touch upon a few more potential technological constraints related to total size.

Scaling Rates

Now that we have a target and a timeline, we can establish the required “scaling rate.” Once this is in place, we can start to think about questions like “What constrains scaling rate?” and “What are the requirements that a technology must have to scale at this rate?”

Digging into this subject, one of the things that surprised me the most is how feasible this goal actually is. Everyone who has worked in the solar industry is familiar with solar’s historical growth curve – an exponential increase since 1975 averaging somewhere around 30% per year, which is pretty astounding on its own. What I had never seen until I made the graph myself is how the rate of increase correlates with annual production capacity. Intuitively, one would expect that as the industry grew, it would become harder and harder to maintain exponential growth. This is certainly true in the limit, or the entire universe would eventually be converted into solar panels. However, looking at the data over the past 35 years (especially the past 10 years), we see the opposite trend, i.e. as the industry has grown, the rate of increase has increased as well! This trend is due to both the rapidly dropping cost of solar power and more widespread public acceptance.

Based on this, what growth can we expect over the next 15 years? More importantly, what growth levels do we need in order to achieve our target of 25 TW installed capacity by (or soon after) 2025. Bearing in mind the old Yogi Berra quote, “It's tough to make predictions, especially about the future,” I invented 3 scenarios for discussion. The “aggressive” scenario is simply a best fit to the growth of the past 10 years. While interesting, looking at physical and societal constraints, this scenario is neither possible nor desirable. The “flat” scenario is continued growth at a steady rate equal to the average of the past 10 years. The “front-loaded” growth is something I made up, based on the growth level we’re at now and the desire to have a sustainable industry in the future, while conforming to the bounds of reality.

Scale calculations_Page_2

Photovoltaic industry historical growth and projections

The aggressive scenario reaches 25 TW by 2019, flat just after 2026, and front-loaded by 2025. However, for the front-loaded case the size of the industry in 2023 is about a third that of the flat case. The front-loaded scenario gets us to the goal in the most sustainable and realistic way, as we will see when we discuss scaling constraints.  Furthermore, the size of the industry (annual production) is much smaller in the front-loaded case (3.6 TW) than the aggressive (14 TW) or flat (9.6 TW) cases.  This is essential for the sustainability of the industry, as we don’t want to just stop making solar panels when we reach our goal.  In the front-loaded scenario, the industry can simply stop growing and produce at a level that eventually provides for our entire energy demand, along with replacing panels that have started to degrade after 30+ years.

Again, these aren’t necessarily “likely” scenarios. They are scenarios that both fit with what might physically be possible and achieve the stated scaling goals.

Grid Parity

Before we jump into thinking about different constraints, a note about grid parity (the point at which solar power matches the cost of the current electric grid). Ever since I started working in solar, the incessant drumbeat has been “grid parity.” Somehow, I expected more of a D-Day type celebration when I read that First Solar had achieved this elusive goal (Not that grid parity is the sole possession of First Solar – I have seen convincing cases that string ribbon Si, high efficiency tracked Si, thin-film Si, CIS/CIGS, and CPV technology are there or will be there soon). So, congratulations everyone, we did it! However the reality is that grid parity is a sliding scale, depending on a huge number of factors, but that discussion is too big to get into in this post. In reality, we may have only achieved 20% grid parity, so the quest towards lower cents/kWh continues!

Now we return to the discussion of the path solar growth must follow.

Scaling Rate Constraint 1: System cost and bankability

Even at grid parity, there is a finite amount of investment and money flowing through the economy, which in some sense corresponds to the total amount of effort we as a society can collectively direct towards everything. One measure of this is the worldwide GDP. The main requirement here, simply put, is that the amount of money required for the up-front cost of all solar power systems should not make up a significant portion of the worldwide GDP ($69.7 trillion in 2008); if it does then this is an unreasonable amount of resources to expect.

If we look at the front-loaded growth scenario, $3-6/W system costs are sustainable for the next few years after which point costs will have to start dropping closer to $3/W (approximately current best practice for large thin film installations) However, by 2017 or so, system costs will need to start dropping closer to $1/W or growth will suffer.  This cost reduction roadmap (shown below) falls pretty well in line with solar’s historical cost learning curve.

Scale calculations_Page_1

Projected cost learning curve for solar

I should also note that these $/Wp numbers are for one set of assumptions (18.4% capacity factor, 4.5% discount rate, and 25 year life). As has been shown, actual $/kWh electricity prices can vary quite a bit for systems of similar $/Wp ratings. The point here is to bracket the problem: are we talking about 0.1%, 1% or 10% of the GDP?

Based on the $/W roadmap I mention above, solar energy power systems will consume between 0.1%-5% of the worldwide GDP in the front-loaded growth scenario.  Looking at the graph below, we can see why the aggressive and flat growth scenarios are undesirable – both the level and the rate of increase of total GDP seems effectively impossible near the tail ends of their growth curves.

  Scale calculations_Page_3

Investment requirements for different solar growth projections

The question remains, is the front-loaded growth case reasonable? Technically, yes; therefore it is mainly a social priorities question – do we want to do it? The graph below shows how it compares with some other industries in 2008. I use U.S. GDP numbers, as these are easier to come by, but the picture is similar on a worldwide scale.  On one hand the 2025 GDP requirement is about 2.5 times as large as the current utility contribution to GDP. On the other hand, it’s interesting to note that it is approximately the same percentage magnitude as the decline in U.S. manufacturing GDP over the past 10 years. My take-away is that given positive political and popular sentiment it is well within the bounds of reality, but it is likely still one of the most limiting scalability factors. Grid parity is not enough.

Scale calculations_Page_4

Comparison of projected solar industry size with other US industries

Furthermore, in terms of securing financing, the concept of “bankability,” (in short, the certainty of making money) was discussed quite a bit at Solar Power 2009, as it is becoming increasingly important as the size of systems increase. For solar, this comes down to reliability (both demonstrated and perceived), as well as company balance sheets (a metric of the likelihood that module warranties will be honored). All emerging technologies will have to rigorously address reliability in one way or another to prove to the banking industry that their technology is the Will Smith of Solar. For example, CPV systems must contend with thermal and tracking issues, which is leading to the development of reliability standards; CIGS tends to be more sensitive to moisture ingress and corrosion, leading to innovative module packaging; CdTe must rigorously address life cycle management due to cadmium toxicity concerns.

Scaling Rate Constraint 2: Energy Pay Back Time

Although there was much discussion of high energy pay back time (EPBT) in the 70s and 80s, it is mostly a non-issue today as nearly all PV technologies have a EPBT less than 2 years (i.e. the power produced during the first 2 years of a panels 25+ year operating life will equal the amount of power required to produce it), with some technologies paying back in less than a year. However, when discussing scaling quickly to large portions of the energy supply, even 2 years can look like a long time. Consider if the industry doubled in size every year and the system EPBT was one year; in this case 100% of the energy of the panels produced would go into producing the power required for next year’s increase, thus no net power. I categorize this as power yield, or percent of produced power that is not consumed making and installing increasingly more power.

Based on the front-loaded growth curve, 1 year EPBT gives energy yields of 50-60% in the near term high growth phase, easing off to 70-90% in the longer term. I see this as a minimum metric for scalability. Ideal EPBT would be closer to 0.5 years, which keeps the energy yield in the 80-90% range even during the high growth years.

Scaling Rate Constraint 3: Capital expenditure per watt

This constraint is related to system cost, but also how fast a factory can be scaled up. For capital expenditures (CapEx) we can look at specific historical spending. Looking at government census data, average CapEx per year in the U.S. for all sectors is $1.2 trillion/year, including $200 billion/year for the “manufacturing” sector and $100 billion/year for the “utilities” sector.  With this in mind, CapEx costs <$1/W are almost certainly required, with CapEx costs less than $0.50/W much preferable.

There are a number of companies that have this argument built into their value proposition. For example, Skyline Solar plans to use a combination of already existing auto manufacturing capital and highly leveraged (via concentration) crystalline solar manufacturing capital. Another company which explicitly has this in mind is Nanosolar with their largely non-vacuum printing-based deposition.

Ultimate Size Constraint 1: Material Availability

Recently, some folks at Berkeley did a great study of resource bases and material availability for a whole host of potential photovoltaic materials. This study and others like it have shown that there are some device designs limited by material availability to less than 1 TW/yr (CdTe limited by Te, CIGS limited by In and to a lesser extent Se).  However, there are many other device structures that show effectively unlimited material availability.

Ultimate Size Constraint 2: Energy Storage

The other potential limitation of scale is energy storage.  Energy storage is a huge topic which deserves its own discussion, so I will only touch on some of the strategies being pursued which would enable 25 TW peak electricity to be supplied to the grid.  While some studies in Germany have found that up to 30% of peak electrical demand can be supplied via solar energy without significant modification of existing infrastructure, much deployment beyond that will depend on a number of energy storage technologies.  Some envision the widespread use of compressed air energy storage. CSP with massive amounts of thermal energy storage appears to be another potential solution.  Yet another viable strategy is vehicle-to-grid, or V2G.  The idea is to use the distributed storage capacity that will come with increased deployment of electric cars and plug-in-hybrid vehicles, especially with newer advanced battery technologies. Finally, the holy grail of energy storage technology is direct solar fuel.  The basic idea is: instead of converting solar energy into electrical energy, convert it into chemical energy in liquid or gaseous form, enabling temporal and spatial separation of generation and use.

Ultimate Size Constraint 3: Labor

While less of an inherent constraint than the others listed, this is certainly something to consider. At the cycle time session at Solar Power 2009, Laks Sampath mentioned that “best practice” large scale ground mount installations took about 4 h/kW to install. If we look at the growth projections, this number will have to come down by an order of magnitude by the end of the next decade, otherwise somewhere around 7 million people (worldwide) will have to be employed simply installing panels. Although this number is not completely absurd (in the U.S., the entire construction industry employs around 11 million people), it seems likely and desirable that this number can be drastically reduced. This could be accomplished in ways similar to the innovations shown by Applied Materials with their gen 8.5 module, SunPower with their T20 tracker, or SunTech with their Reliathon module. As a reference number, the Apollo program at its peak employed 400,000 people.

Ultimate Size Constraint 4: Land

Most studies on this issue have concluded that it is not a constraint. To make this easier to think about, we’ll only consider the United States’ portion of energy use. For the United States’ energy needs, depending on efficiency, array packing density, insolation, and other factors, this number is somewhere around 1-2% of the land area of the U.S.. It is similar in magnitude to the total paved area of all roads and parking lots in the U.S. It is also the same order of magnitude as the total area reserved for U.S. military bases and bombing ranges.

So, on one hand, using this amount of land to provide for a significant portion of our energy needs seems like a relative non-issue. On the other hand, it is huge! On average, just for the U.S. portion of energy demand, we will need to install 10 square miles (~6,700 acres) every single day for the next 15 years (assumes 10% AC module efficiency and 40% packing density). Thinking about installing PV over an area of that size in a day is admittedly quite daunting. Not insurmountable, but daunting.

To look at it on another scale, I spread the 5 TW of PV to be installed in the U.S. into 50 evenly sized installations across the nation (square installations 34 miles on a side). I put a few more in the sunnier states, but the distribution is mostly random, trying to avoid national forests/parks. Somehow, visually, this seems more doable, as I can imagine 50 separate teams working for 15 years rather than 1 team of a few hundred thousand working in the same place. Or, in the (admittedly silly) extreme case, over the next 15 years, each of the 304 million people in the U.S. would have to go outside and install one 220 W panel every other month. People between 16-65 would have to pick up the slack for those who couldn’t install solar panels, but it is still about the same magnitude of effort as a regular household chore. In one sense, the beauty of solar (at least PV) is that it works on anything from kW scale to GW scale.

 50USboxes Land area of solar needed to provide 5 TW peak power to the US


Parting thoughts

There is no doubt that solar power at this scale will be mind-bogglingly huge compared to its current scale. However, it is entirely within the realm of physical and societal constraints. Cutting through the hype, I’ve found there are a few fundamental metrics of scalability to keep in mind when assessing technological innovations and strategic directions.

To quote a solar pioneer (MIT Professor Ely Sachs), "The science is understood, the material abundant, the product works, all that is left is to build the biggest manufacturing industry in the history of human kind. Time is a-wasting."

Standards for Photovoltaics

Max Davis, November 17, 2009

I recently returned from a week spent as one of the US representatives on the IEC Technical Committee 82 (TC82), which develops standards for solar photovoltaics. My focus is on Working Group 7, where we are working on standards including solar trackers and power and energy rating of concentrating photovoltaic modules. However, meeting with the rest of the TC82 community also gave me an opportunity to discuss issues in the design and testing of conventional wafer-based and thin-film modules.

While there are a number of groups working on standards applicable to solar (including the UL, ASTM, and NEC in the United States, CENELEC in Europe, and IEC and ISO internationally), the IEC plays an especially significant role because photovoltaics is a global market: major producers of polysilicon, cells, modules, and tools are spread across Europe, Asia, and the Americas, and customers are worldwide as well. Similarly, TC82 has members from 29 countries (including the major markets; China, Spain, Germany, the US, Japan, and France) working together to develop standards.

China and US

Standards are an important part of any growing industry.  For example, the SEMI International Standards Program is widely credited with speeding the growth of the semiconductor industry since the 1970s. Looking back, it’s hard to believe that at one point wafer sizes and shapes were not standard, and “custom-made solutions for each individual customer were the norm”[1].

For an industry whose value proposition depends on long product lifetimes in outdoor environments, standards that govern design qualification, accelerated testing, and safety of products are especially important. Additionally, standards for power rating, energy rating, and measurement are critical for allowing side-by-side comparison of different products.  This is especially apparent when trying to compare between crystalline PV, thin-film PV, and CPV.

Some of the PV standards we find most relevant in our work[2] are listed below. Where possible, I’ve also linked to free previews of the table of contents of each standard:

  • IEC60904: Photovoltaic Devices
    • This is a large, ten-part standard (IEC60904-1 is the numbering scheme for part 1, and so on) covering a number of device characterization areas such as measurement of I-V curves, spectral response, and solar simulators.
  • IEC61215 (ed2.0, 2005): Crystalline silicon terrestrial photovoltaic (PV) modules: Design Qualification and Type Approval
  • UL1703: Flat-Plate Photovoltaic Modules and Panels
    • Note that this is also applied to thin film modules and in some cases in the past concentrating modules, though see also UL8703 below.
  • IEC61646 (ed2.0, 2008): Thin-film terrestrial photovoltaic (PV) modules: Design Qualification and Type Approval
  • IEC62108 (ed1.0, 2007): Concentrator photovoltaic (CPV) modules and assemblies: Design Qualification and Type Approval
    • Note that for low concentration (<10x) modules, it is less clear whether they will be tested under IEC 62108 or an adapted form of IEC 61215. And some concentrating systems such as heliostats differ from the main focus (no pun intended…) of IEC 62108.
    • On the IEC committee we are actively soliciting feedback on the first edition, as we work on a second edition.
  • UL8703: Concentrator Photovoltaic Modules and Assemblies
  • UL1741 and the just-published European standard EN50530 cover inverters
  • The PV Resources web site contains a more exhaustive list of standards, though it is somewhat out of date and does not mention some of the newest standards. And the standards above cover a significant portion of what companies we work for care about.
  • You may also find this UL diagram of UL/IEC PV standards by system component informative.

For anyone who was new to the industry, I hope this list of information is useful. 

That said, qualification standards only outline the bare minimum testing. It’s important to design tests to simulate other failure modes and environmental conditions not included in the standards. In addition, testing identifies certain failure modes that are more systematic (damp heat for the previous generation of thin-film modules, for example), helping guide areas for design.  Including testing early in the development path is important: we have seen some companies develop a first prototype, only to require major design revisions once they begin thinking about reliability, DFM, and qualification. 

The topic of PV module design for reliability could be a whole separate discussion, but two documents to get you started down this path are:

Standards themselves don’t necessarily inspire passion and dedication in everyone, but their purpose overlaps with the desire to design and build high-quality, reliable, cost-effective technologies that can solve some of our pressing energy supply and environmental issues. And doing that makes us at GreenMountain very excited. Come back to this blog next week for a post about the scalability of solar, examined from a variety of perspectives (land usage, capital requirements, labor, and growth rate). 

[1] The SEMI International Standards Program – History, Successes and Lessons Learned to Address Compound Semiconductor Manufacturing Challenges, http://www.csmantech.org/Digests/2006/2006%20Digests/4A.pdf

[2] I'm putting the "about us" blurb down here in a footnote as many readers may already be familiar with us: We offer design engineering for hire, including engineering of products, automated tools, and software for many companies in the cleantech sector. This includes extensive experience in the solar industry (we’ve done design engineering for dozens of solar companies). The product-related standards I mention in this post are less relevant when we develop manufacturing tools, but do come into play when we design solar modules, encapsulation, interconnects, CPV receivers, or a range of other solar components.

Highlights from the 5th Conference on Clean Energy in Boston

Brandon Stafford, November 12, 2009

Matt, Jon, and I went to the Conference on Clean Energy at the Hynes Center in Boston today. This morning, I watched a series of investor pitches from a group of cleantech startups. The mix was interesting-- smart grid startups were dominant, which is a big change from the last few years, where solar, wind, and biofuels were the big players.

To my ear, the most interesting pitch was from the least clean of the startups-- Silicon Basis. They're an integrated circuit company; the "clean" angle is that their chips will have lower power consumption.

Dave Richards, a charming Englishman from the University of Bath, spoke in place of CEO Rob Beat. Silicon Basis is trying to implement a new type of chip that has lower power consumption and better performance (600 MOPs/mW) than the typical chips used in cellphones, ipods, and the like, but with a reconfigurable technology that will reduce development time and cost substantially below the usual 18-24 months and $10M. In technical terms, they say they've figured out how to manufacture FPGAs that reconfigure themselves between clock cycles. If they have actually pulled this off, they are insanely smart. About 2 months ago, they were issued patent GB2457912 in the UK. Silicon Basis also announced a partnership with Actina Imaging, who will help them test their first chips.

Here are brief summaries of the other startups that pitched.

Jason Hanna, President and Founder of Coincident Smart Energy Technology

Jason is a computer engineer out of EMC. I talked with him for a few minutes after the talk; he seemed like a smart engineer. Coincident is developing two things: an online marketplace for HAN devices and services and a hardware gateway. From my perspective, the hardware gateway was more interesting-- an embedded Linux board with a Zigbee wireless module. On looking at their website, I realize that I had found it a few months ago-- I'm impressed that they managed to get coincident.com.

Steven Filler, Director of Business Development, Prism Solar

Prism Solar is building holographic concentrators for solar panels by replacing 70% of the silicon with strips of holographic film. I was inclined to like Filler's presentation because it included a lot of numbers. Their holographic film selects part of spectrum for efficient heat rejection, which results in 10 C cooler cells at high noon in Tucson as compared to a conventional solar panel. Filler claimed that their holograms have better acceptance angle and can use bifacial cells. He claimed a 70% increase in energy production. Prism is selling modules domestically, but really wants to sell holographic film under license. They think they can hit 1.04 $/W by 2012.

Rory Gaunt, CEO, Lifecycle Renewables

The most interesting part of Rory Gaunt's presentation was the bullet: "negligible technology risk." Lifecycle Renewables' plan is to convert waste vegetable oil into fuel for commercial electricity and heat.
Whole Foods Market will be their first oil supplier and customer in 2010 when they bring up a 500 kW station, taking a 45,000 ft2 kitchen facility off the grid. Their claimed advantages over other biofuel heat/power startups are low cost processing, efficient logistics technology, and state and federal incentives. They're seeking $750k and plan to be profitable in year 2. I like Mr. Gaunt's straight-forward style: "Funds will be used to get the oil."

Roselyn Romberg, Electronic Housekeeper

Founded in Denmark in 2005, Electronic Housekeeper launched in Europe in Q1 2008. They plan to establish a new headquarters in the US shortly. They make smart grid hardware hub for apps and services with backend database. They've had $1M in sales so far, and they claim that their customers' have seen usage reductions of 10-15% in electricity, 15-25% in gas, and 20-40% in water. I thought it was interesting that Ms. Romberg emphasized their device's passive nature: "We don't rely on behavior modification."

Roger Faulkner, Electric Pipeline

Cost-effective underground power transmission. I'm afraid don't know much about power transmission, so I didn't listen to Roger carefully. Sorry, Roger.

Dave Howell, COO of Practical Solar

Practical Solar is making heliostats with a total cost of $200/m2. Howell viewed the proprietary firmware in their controller as a strength, and he boasted about how difficult it would be to reverse engineer it, taking more than a year and a million dollars to do so.

Mitch Wondolowski, Grid Solutions

Weather, market prices, and utility rates integrated into a residential demand response system.
"Enabling residential load balancing for the grid"

Richard Chase, Future Solar Systems

If I understood Mr. Chase correctly, Future Solar will install solar panels using an arrangement similar to that used by the City of Berkeley in California-- they put up the capital to put solar panels on your roof, and then you pay them for the electricity over the next 20 years. (Not exactly the same as Berkeley, but similar.)

That was all in the first session on Thursday. If i have the time, I'll add more summaries from the rest of the conference tomorrow.

Rooftop testing station site goes live

Jon Chambers, October 30, 2009

John Lawler mentioned our rooftop testing station back in April. We've undertaken a fun project over the last couple of weeks, and I'm pleased to announce our web site that shows data from the instruments in our rooftop solar testing station. You can check it out at http://roof.greenmountainengineering.com/.

Rooftop-station

Data is recorded whenever the sun is up in San Francisco and is displayed "live" (well, actually updated every 60 seconds) for the current day. If you select a day in the past from the calendar, you'll see data from that day. You'll also get a fancy time-lapse video showing the weather conditions for that day.

Although the setup is explained in much more detail on the actual site, the very short version of how this all works is that we have a computer in a weather-proof case on the roof. The computer collects data from all of the various instruments and sensors (including a Trac-Stat SL1) and sends it off to our web server. Our web server stores that data, processes it, and sends it to you in the form of a web site.

This whole arrangement is a simple analogue for a number of projects we've done for our clients. Although our rooftop testing station site shows off a publicly-accessible, read-only interface to a single set of equipment, we've built secure systems to control and monitor hundreds of discrete pieces of equipment simultaneously, log hundreds of gigabytes of data per year, and provide convenient access to equipment in remote locations.

Please let us know if you have any questions about the site or if you'd like to learn more about the kinds of things we can do to develop monitoring and control systems for you.

EUPVSEC Presentation and Poster Highlights

Max Davis, October 23, 2009

As a follow-up to my post a few weeks ago about the 2009 EUPVSEC (EU PVSEC 24), the following presentations were the ones I personally found most interesting (I've also uploaded a copy of the program for the oral sessions, which contains author information for these).

  • 2AO.3.4 Boron-Oxygen Related Defects in Cz-Silicon Solar Cells: Degradation, Regeneration and Beyond
  • 2AO.3.5 Quantitative Stress Measurements of Bulk Microdefects in Multicrystalline Silicon
  • 2BP.1.3 High Efficiency n-Type Si Solar Cells with Front Side Boron Emitter
  • 2CO.3.2 Crystalline Si Solar Cells with Selective Emitter for Industrial Mass Production
  • 3CO.6.3 Epitaxial Thin Film Silicon Solar Cells Fabricated by Hot Wire Chemical Vapor Deposition Below 750°C
  • 3CO.7.2 Epitaxy Wrap-Through Rear Contact Solar Cell Fabrication and Results
  • 4CO.5.3 World Record Module Efficiency for Large and Thin mc-Si Rear Contact Cells
  • 4CO.5.4 Analysis of PV Modules by Electroluminescence and IR Thermography
  • 2DP.2.2 Kerf-Free 20-150μm c-Si Wafering for Thin PV Manufacturing
  • 2DP.2.5 Physical Mechanisms of Breakdown in Multicrystalline Silicon Solar Cells 
  • 4EP.1.3 Results of 5 Years Module Manufacturing Research In European ‘Crystal Clear’ Project    

I also browsed or skimmed nearly 900 posters while there; below are just a selection of ones I found interesting (see the program for the visual presentations for more information):

  • 2CV.2.2 Investigation for 19% Efficiency at Multi-Crystalline Si Solar Cells by Industrially Probable Approach 
  • 2CV.2.3 Advances in Electroless Nickel Plating for the Metallization of Silicon Solar Cells Using Different Structuring Techniques for the ARC
  • 2CV.2.8 Laser Processes for Industrial Manufacturing of Solar Cells
  • 2CV.2.13 Microstructure and Mechanical Properties of Aluminum Back Contact Layers
  • 2CV.2.78 High Efficiency HIT Solar Cell on Thin (<100 μm) Silicon Wafer  
  • 2CV.5.83 Inkjet Texturing for Multicrystalline Silicon Solar Cells
  • 3AV.1.12 Hybrid Excimer Laser and Aluminium Induced Crystallisation of Silicon Thin Films
  • 4AV.3.2 The Evaluations of Physical Properties and Lamination Process Parameters of EVA Encapsulants by Thermal Analysis 
  • 4AV.3.39 Characterization of Thermo-Mechanical Behavior of Ribbon and Solder Materials
  • 4AV.3.54 The Effect of Accelerated Aging Tests on the Optical Properties of Silicone and EVA Encapsulants

Thin-Film Solar: Interpreting Efficiencies

Max Davis, October 19, 2009

Reporting the efficiency of a solar cell or module depends on a number of assumptions, and unrealistic assumptions are sometimes made in order to report the highest possible efficiency.

There are some cases where it is difficult to make fair and consistent assumptions. For example, when comparing different technologies (thin film, crystalline silicon, and CPV) which have different values for temperature coefficient, spectral dependence, land coverage, and other properties, it can be difficult to come up with a completely standard, comparable, and realistic method of rating power and efficiency.

However, within a particular type of technology (thin-film solar, for example), there is really no excuse for making non-standard assumptions and then omitting this critical information when you report your results. For this post I’m going to focus on particular misleading reporting practices I have seen used multiple times in the thin-film industry (that is, solar technologies such as CIS, CIGS, CdTe, and thin-film silicon, which includes amorphous silicon, and “micromorph” tandem devices).

I do understand that this poses a challenge to each individual company: If your competitors are reporting their efficiency in a misleading way, it is difficult to report your own results in the “correct” way if it gives the appearance that you have a lower-efficiency product. This is a form of arms race or “Prisoner’s Dilemma”, but this is also not my problem: my point here is to make sure people who read results know the right questions to ask to make sure companies are giving them realistic numbers with full disclosure on the most critical measurement assumptions.

Assumption: Aperture Area

One detail often glossed over is the notion of aperture area compared to full area. An aperture area efficiency for a module divides the output power by only the area covered with the active absorber, not including the border around the module where the edge seal is or the frame. In addition, in some cases (especially during R&D), companies mask or scribe away regions of the absorber where there is significant thickness variation due to edge effects in the deposition chamber, and don't include those edge regions in the measurement. A 25mm border on a Gen 5 glass sheet (1.1 x 1.4m) corresponds to about an 8% relative difference in area, or a roughly 1% difference in reported absolute efficiency for a 12% efficient module.

Note that in some cases aperture area is a reasonable way to report efficiency, especially during R&D when you want to report the overall potential of a technology and ignore some process issues, or if the deposited materials are a large fraction of your cost and your substrate is a low-cost plastic (in which case extra area of this plastic may not add as much cost as active module area). However, it’s important to clearly state that an aperture efficiency is what’s being reported.

Assumption: Light-Induced Degradation

Another reporting issue most relevant to thin-film silicon is the reporting of initial efficiency compared to stabilized efficiency. Stabilized efficiency is the relevant number for real-world applications, and refers to performance after the degradation that amorphous silicon undergoes when exposed to light for the first time (the Staebler-Wronski effect, also referred to as LID for Light Induced Degradation). However, some companies report the higher initial/unstabilized efficiencies, and only mention this is what they’re doing if you ask them directly “is that a stabilized efficiency?” This is important because a typical Staebler-Wronski degradation can be 10% relative, or even more. At the recent EUPVSEC, a number of companies mentioned that their LID at the cell level was 10%, but then were vague about their LID at the module level, or said something along the lines of “there are some challenges with LID on large area [Gen 8.5 glass = 2.2m x 2.6m!] modules,” effectively telling the audience that LID was significantly worse than 10% in their modules.

In other cases, thin-film manufacturers would report the power output and area of modules, but not the efficiency, or even the area, initial power, initial efficiency, and stabilized power, but not the stabilized efficiency. This is a bit silly, as anyone in the room can calculate the stabilized efficiency from these numbers.

So, thin-film manufacturers: If you’re going to show the performance of a new cell or module in a conference presentation, I suggest you include a summary table like the below, rather than making your audience guess or ask you about your assumptions. It only takes one slide, and saves everyone time; and if you don’t do this, savvy people in the audience realize you’re trying to pull the wool over their eyes when you are vague about your measurement conditions.


 

 

Area

Power [W]

Efficiency [%]

LID [% relative]

Cell

Initial

Aperture Area

1 cm2

 

 11.1%

 

Cell

Stabilized

Aperture Area

1 cm2

 

 10.0%

-10%

Module

Initial

Aperture Area

 1.5m2

 143

 9.3%

 

Module

Stabilized

Aperture Area

 1.5m2

 123

 8.0%

-14%

Module

Initial

Total Area

 1.5m2

 136

 9.1%

 

Module

Stabilized

Total Area

 1.5m2

 116

 7.8%

-14%

(the numbers above are arbitrary, just to provide an example)

Or if you really don’t want to use a table, a least attach the most relevant test details to your reported values, for example:

  • 10.4% (1cm2 Cell, Aperture, Stabilized)
  • 9.3% (Gen 5: 1.1x1.4m, Module, Aperture, Initial)
  • 8.7% (Gen 8.5: 2.2x2.6m, Module, Aperture, Initial)
  • 7.8% (Gen 8.5: 2.2x2.6m, Module, Aperture, Stabilized)

Assumption: Deposition Rate

Another question to ask when new efficiency results are reported is: “What was the deposition rate used to achieve the reported efficiency, and is that a realistic throughput according to your cost models?”

Typically, film quality and electrical efficiency go down as the deposition rate goes up. So a company may be able to get a higher efficiency “champion” module by using a very low deposition rate (one that is too low a throughput for volume manufacturing) when making that particular module. This result does have some value: it shows that a certain module efficiency is technically possible on large areas, and perhaps in the future with improved tools and processes, that efficiency might be achievable in manufacturing.

However, in production, companies can run cost models and pick some deposition rate that is a balance of throughput and module efficiency that leads to the best overall cost per watt and cost per area for the module. It’s not a trivial calculation because as efficiency goes down, module area at a given power goes up, so balance of system costs such as installation and land also go up slightly. But it’s also not economically sensible to use a process with dramatically lower throughput just to get an extra 0.1% of efficiency.

Assumption: Deposition Process

Another issue to consider is whether the fabrication processes used are industry standard ones, or less-used processes. If the latter, is there a path to scale-up of the process? It is certainly acceptable to explore new deposition processes in pursuit of better performance, lower cost, or even proof-of-concept devices. However, if a company is presenting results in an established industry where there is a common deposition tool and method (for example, a-si deposited by 13.56MHz PECVD), the company should identify if their devices were made with a different process (VHF plasma, HWCVD, or so on).

Conclusions

There are a number of common ways in which efficiencies reported by thin-film solar companies can be difficult to interpret and compare, based on variation in how the numbers are calculated. Three of the most critical are whether an aperture-area measurement is made, whether light-induced degradation of thin-film silicon is included, and whether the deposition rate was unrealistically low. It is the responsibility of companies to clearly disclose their measurement assumptions, and also of people receiving results to demand this disclosure. I have included a very simple table for reporting results which would avoid the need for perhaps 40% of the questions I have heard asked of thin-film manufacturers at conference presentations. Now let’s all get back to engineering and solving problems!

EUPVSEC Highlights

Max Davis, October 12, 2009

As I thought about how to summarize my week at EUPVSEC 24 in Hamburg, I decided to (mostly) not talk about what record efficiency results were reported by what group. This type of information is already reported by many other blog posts, press releases, and news aggregators, and specific efficiency numbers can be misleading taken out of context. For these sorts of numerical summaries I recommend checking out this PDF of Heinz Ossenbrink's summary presentation given on Friday at EUPVSEC. 

Instead, I'm going to summarize my impressions of the show in several technical areas, and talk about other things that may be harder to get a feeling for by just reading the published papers later. This post will also primarily focus on the technical and poster sessions and related discussions, not the trade show. If you have any questions, feel free to email me at mdavis (at) greenmountainengineering.com, or leave a comment on this blog post.

As this is a fairly long post, here is an overview of the topics:

  • Silicon cells and modules
  • Thin film
  • Wafer equivalent thick film / thin film cells
  • Reflectors
  • Characterization and modeling
  • Inverters and grid interconnections
  • Other technologies
  • Changes in the business climate [future blog post] 

Silicon cells and modules:

There continues to be substantial exploration of—and room for innovation in—new cell designs and manufacturing-scalable fabrication processes in the primary solar technology: crystalline silicon. This includes improved or lower-cost materials (for example, adaptation of metallurgical-grade silicon to solar cells, reduction of the effects of Boron-Oxygen defects in p-type material, and so on), as well as improvements in cell architecture (such as improved texturing for light trapping, metallization, selective emitters, surface passivation, and more significant changes in cell architectures such as rear-contact cells and heterojunctions).

While a variety of improvements in all of these areas have been demonstrated by research groups in the past and integrated into some manufacturing processes, a number of proposed improvements have not yet been widely adopted. This is both because there is still engineering to be done to come up with scalable, cost-effective implementations, and because any new material or process comes with some technical risk and thus must be demonstrated as reliable in the field before major scale-up. Selective emitters do continue to be an area of scale-up, with at least one Chinese manufacturer now using them in a production module design, and other companies selling turnkey wafer manufacturing lines that include a particular selective emitter process.

Progress also continues to be made on fabrication of thinner silicon wafers (e,g, Silicon Genesis’s cleaving process, as well as a number of wire saw optimization projects), and cells (a number of presentations were made on results obtained on cells 120 microns or thinner, including Sanyo’s poster on their impressive >22% efficient, 98um-thick cell based on their HIT technology).

However, reliable, high-yield integration of cells this thin into modules will be a challenge. Towards this end, the EU Crystal Clear project—particularly, sub-project 5: modules—showed some success using rear contact cells with electrically-conductive adhesives and a printed-circuit-board-style backplane to enable a lower-temperature, closer-packed, lower-stress method of module fabrication. Advent Solar is also an example of a company integrating rear contact cells onto a backplane (described and shown in a video on their web site).

IMG_0662
Image: ECN monolithic backplane for use with rear contact cells

There were also a number of companies discussing—and in some cases demonstrating manufacturing tools for—non-contact metallization techniques (e.g. jet printing combined with electroplating, for example), other non-contact processing techniques (e.g. laser soldering, use of laser ablation or jet-printed resists for patterning of dielectrics), and low-stress wafer handling methods. 

Non-contact processing techniques are one way of reducing wafer damage during processing, but there are a range of other challenges to fabricating reliable modules with thin cells.

Thin Films

There were fewer presentations on CdTe and CIGS than I’m used to at conferences, though that doesn’t mean that substantial work isn’t being done in that area; the thin-film production leader First Solar rarely presents at conferences, for example, and we’ve worked with a number of other CIGS and CdTe startups at various levels of stealth that also choose not to present on their work.

There were a number of presentations on thin-film silicon, though, both from research groups and manufacturers. In summary, groups are getting to stabilized module efficiencies of 6 - 7% for a-si (amorphous silicon) and 8.0 - 9.5% for micromorph (a tandem junction a-si/uc-si). But there are many measurement and reporting details to look at carefully when people report thin-film silicon efficiencies (e.g. initial vs. stabilized, aperture area vs. full area, overall size, and what the deposition rate was and how reasonable a throughput that is for manufacturing– to name just a few). I'll comment further on interpreting and understanding thin-film efficiencies in a future blog post

Thick Films / Wafer Equivalent Thin Films

One of the most notable changes—which may partly just be a change in my perception—was the number of people pursuing what were sometimes called “wafer equivalent” devices. These are crystalline cells typically in the 10-30um thickness range, grown on a substrate (one example architecture is shown below).

IMG_0603
Image: one architecture for wafer-replacement crystalline silicon, presentation 3CO.6.3 by NREL

For example, a cell could be grown by gas-phase epitaxy on a lower-quality metallurgical-grade silicon cell “template”. Or, an amorphous silicon layer could be deposited on a substrate by some rapid, lower-than-usual-quality CVD process and then crystallized, using a laser, metal-induced crystallization, or solid phase crystallization. These methods could even be combined, to deposit and crystallize a thin seed layer by one technique, and then use epitaxy to grow a thicker crystalline layer on top of the seed layer. Companies like CSG Solar have pursued one approach towards polysilicon cells (deposition of a-si on glass followed by solid phase crystallization), but there a variety of significantly different approaches being pursued—this is a fairly broad technical category.

There were a number of presentations in this field, and I’m also aware of a number of stealth companies pursuing variations on these techniques. I find this interesting because the semiconductor industry has addressed similar challenges in the past, and there is potential for the solar industry to bring in experience from research in the IC and LCD TFT backplane industries.

Reflectors

Reflectors are important for improved light trapping in technologies including thin-film modules, thick-film “wafer equivalent” cells described above, and even conventional multicrystalline silicon wafers.. This is an area where there will continue to be significant development beyond the basic chemical texture etches that are effective for single-crystalline silicon wafers.

Materials, Characterization, and Modeling

Most of the usual characterization techniques for materials, cells, and modules were discussed, such as EBIC, EBSD, SIMS, XRD, IR imaging of various types, EL (electroluminescence), PL (photoluminescence), Raman spectroscopy, and so on. But I also saw presentations on some methods new to me, such as: photoelasticity (a mechanical-optical method for examining defects by looking at the stress fields produced by them) and Dynamic ILM (infrared lifetime mapping, but based on a chopped light source and looking at the shape of the resulting waveform).

There were also a number of discussions about dopants and impurities in silicon, as well as various methods for characterizing, modeling, and reducing the effects of them.

Inverters and grid integration:

The European inverter standard EN50530 has finally been released, and includes some provisions for how to characterize the behavior of inverters’ MPPT (maximum power point tracking) algorithms, a method by which the inverter tries to operate a solar module at the current and voltage of maximum power rather than at a fixed voltage.

As solar (and other intermittent-supply renewable energy technologies such as wind) grows to be a more significant contribution to electricity production in some countries, utilities are taking it more seriously. This leads to additional requirements (and opportunities to add value) for inverters, including the ability to supply reactive power and in other ways contribute to grid stability, as well as the ability to stay connected and ride through low voltage events or grid failures, in part to avoid cascading shutdowns of more and more plants if grid voltage drops (Germany has learned some lessons in this area with the growth of the wind industry there and some grid issues).

Other Technologies:

Some further progress has been made in areas such as intermediate band cells (using quantum dots or bulk materials) and organic photovoltaics, as well as in building integrated PV, but I don’t see any of these becoming significant in the near term.  That is not to say they won’t have niches that are profitable for the companies involved, but they are unlikely to contribute a significant portion of the total gigawatts of installed PV capacity.